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91.
《Ceramics International》2022,48(4):5312-5320
Ce3+ and Pr3+ co?doped Lu3Al5O12 phosphors were synthesized by the sol–gel process, and their crystal structure, photoluminescence (PL) properties, and energy transfer (ET) from the Ce3+ to Pr3+ were studied. The Lu2.94?yAl5O12:0.06Ce3+, yPr3+ phosphors (0.002 ≤ y ≤ 0.008) showed the green?yellow emission from the 2D3/2 → 2F5/2, 7/2 transition of Ce3+ and the red emission at 610 and 637 nm, which were caused by the 1D2→3H4 and 3P0→3H5 transitions of Pr3+, respectively. The optimal concentration of Pr3+ for efficient ET was found to be x = 0.006. The electric quadrupole?quadrupole interaction was responsible for the concentration quenching in the Lu2.94?yAl5O12:0.06Ce3+, yPr3+ phosphors, based on Dexter's theory. The incorporation of Pr3+ for Lu3+ enhanced the red PL intensity in the Lu2.94Al5O12:0.06Ce3+ phosphor. 相似文献
92.
93.
《Journal of the European Ceramic Society》2022,42(11):4479-4492
ZrB2-MeC and ZrB2-19 vol% SiC-MexCy where Me=Cr, Mo, W were obtained by pressureless sintering. The capability to promote densification of ZrB2 and ZrB2-SiC matrices is the highest for WC and lowest for Cr3C2. The interaction between the components results in the formation of new phases, such as MeB (MoB, CrB, WB), a solid solution based on ZrC, and a solid solution based on ZrB2. The addition of Cr3C2 decreases the mechanical properties. On the other hand, the addition of Mo2C or WC to ZrB2-19 vol% SiC composite ceramics leads increased mechanical properties. Long-term oxidation of ceramics at 1500 °C for 50 h showed that, in binary ZrB2-MexCy, a protective oxide scale does not form on the surface thus leading to the destruction of the composite. On the contrary, triple composites showed high oxidation resistance, due to the formation of dense oxide scale on the surface, with ZrB2-SiC-Mo2C displaying the best performance. 相似文献
94.
In the current research, a modern learning machine algorithm named “Weighted Regularized Extreme Learning Machine (WRELM)" is implemented for the first time for the simulation of the coefficient of discharge of side slots. For this purpose, an effective variable on the coefficient of discharge of side slots is firstly introduced, then five distinctive WRELM models are produced by it for the estimation of the coefficient. In the next stage, a database is created for verification of WRELM results. it should be mentioned that 70% of the data are utilized for training the WRELM models, while the rest (i.e. 30%) for testing them. After that, the optimal number of hidden layer neurons as well as the best activation function of the WRELM algorithm are chosen. In addition, the best regularization parameter and also the weight function of the WRELM are achieved. By conducting a sensitivity analysis, the most effective variable for the simulation of the coefficient of discharge along with the WRELM superior model is introduced. The WRELM superior model estimates values of the coefficient of discharge with the maximum exactness and the highest correlation. For instance, the estimations of the correlation coefficient and scatter index for this model are computed to be 0.930 and 0.051, respectively. The sensitivity analysis shows that the ratio of the side slot crest height to its length and the Froude number should be considered as the most important input variables. A comparison between the WRELM with the ELM displays that the former works much better. Furthermore, an uncertainty analysis is executed for both models. Eventually, an equation is suggested for the estimation of the coefficient of discharge and a partial derivative sensitivity analysis is performed on it. 相似文献
95.
Imbalance vibration is a typical failure mode of rotational machines and has significant negative effects on the effii-ciency,accuracy,and service life of equipment.To automatically reduce the imbalance vibration during the opera-tional process,different types of active balancing actuators have been designed and widely applied in actual produc-tion.However,the existing electromagnetic-ring active balancing actuator is designed based on an axial excitation structure which can cause structural instability and has low electromagnetic driving efficiency.In this paper,a novel radial excitation structure and the working principle of an electromagnetic-ring active balancing actuator with a combined driving strategy are presented in detail.Then,based on a finite element model,the performance param-eters of the actuator are analyzed,and reasonable design parameters are obtained.Self-locking torque measurements and comparative static and dynamic experiments are performed to validate the self-locking torque and driving effi-ciency of the actuator.The results indicate that this novel active balancing actuator has sufficient self-locking torque,achieves normal step rotation at 2000 r/min,and reduces the driving voltage by 12.5%.The proposed novel balancing actuator using radial excitation and a combination of permanent magnets and soft-iron blocks has improved electro-magnetic efficiency and a more stable and compact structure. 相似文献
96.
Amyloid precursor protein (APP) is a type 1 transmembrane glycoprotein, and its homologs amyloid precursor-like protein 1 (APLP1) and amyloid precursor-like protein 2 (APLP2) are highly conserved in mammals. APP and APLP are known to be intimately involved in the pathogenesis and progression of Alzheimer’s disease and to play important roles in neuronal homeostasis and development and neural transmission. APP and APLP are also expressed in non-neuronal tissues and are overexpressed in cancer cells. Furthermore, research indicates they are involved in several cancers. In this review, we examine the biological characteristics of APP-related family members and their roles in cancer. 相似文献
97.
98.
H. Alrobei M.K. Prashanth C.R. Manjunatha C.B. Pradeep Kumar C.P. Chitrabanu Prasanna D. Shivaramu K. Yogesh Kumar M.S. Raghu 《Ceramics International》2021,47(7):10322-10331
In the present study we made an effort to deploy eco-friendly synthesized reduced graphene oxide/Lanthanum Alluminate nanocomposites (RGO-LaAlO3) and Lanthanum Alluminate (LaAlO3) as adsorbents to remove dye from the synthetic media. XRD, SEM, BET surface area and EDX have been used to characterize the above-mentioned adsorbents. The impacts of different factors like adsorbent dosage, the concentration of adsorbate and PH on adsorption were studied. The best fit linear and nonlinear equations for the adsorption isotherms and kinetic models had been examined. The sum of the normalized errors and the coefficient of determination were used to determine the best fit model. The experimental data were more aptly fitted for nonlinear forms of isotherms and kinetic equations. Pseudo-second-order and Freundlich isotherm model fits the equilibrium data satisfactorily. Methyl orange (MO) has been used as model dye pollutant and maximum adsorption capacity was found to be 469.7 and 702.2 mg g?1 for LaAlO3 and RGO-LaAlO3, respectively. 相似文献
99.
Guilherme M. Martins Cristiano Fantini Roberto L. Moreira Anderson Dias 《Ceramics International》2021,47(11):15202-15209
In this work, Gd2Ge2O7 polymorphs were obtained by solid-state reactions at 1100–1300 °C. Structural and vibrational features were investigated by X-ray diffraction and Raman spectroscopy. For the triclinic (space group P1) polymorph, all the predicted phonons were discerned in perfect agreement with the group theory calculations, while for the tetragonal polymorph (space group P41212), 53 bands of the 81 predicted modes could be identified and characterized. The Gd3+ 4f-4f electronic transitions were investigated by diffuse reflectance spectroscopy in the range 200–340 nm. By applying the Kubelka-Munk function, it was possible to determine the bandgap values for all ceramics studied. The tetragonal polymorph exhibited higher bandgap values (5.88 eV) than the triclinic one (5.59 eV), which are both more energetic than other pyrochlore polymorphs reported in the literature. The results indicate that the presence of polymorphism in Gd2Ge2O7 ceramics can be used to produce tailor-made materials since their crystal structures have a strong influence on their optical properties. Consequently, these properties could be used to tuning the optical properties of Gd-containing materials to sensitize and transfer energy to other luminescent lanthanide ions, aiming for innovative applications. 相似文献
100.
《Ceramics International》2021,47(22):31329-31336
Traditional inorganic materials exhibit rigidity owing to the lack of polymer chains in polymer materials or atom slipping in metals. However, nanometerization has been recently proposed for the conversion of inorganic oxide materials into flexible materials. Herein, the flexible inorganic luminescent material, CaTiO3:0.2%Pr3+, was synthesized through electrospinning, and the macroscopic flexibility of pure inorganic CaTiO3:0.2%Pr3+ was achieved. The flexible membrane was characterized via X-ray diffraction, thermogravimetry, scanning electron microscopy (SEM), and photoluminescence analyses. The grain size was analyzed at various calcination temperatures via SEM, and the results suggested that the increase in the calcination temperature resulted in the growth of crystal grains. Studies have reported that the growth of crystal grains is beneficial for improving the luminescence performance; however, to obtain better flexibility, smaller crystal grains are required. This study provides an important reference for the design of flexible inorganic materials. 相似文献